Synthesis and Characterization of CaO-TiO2 for Transesterification of Vegetable Palm Oil

Authors

1 Department of Chemical Engineering, School of Chemical and Energy Engineering, Universiti Teknologi Malaysia (UTM) Johor Bahru, 81310, Johor, Malaysia

2 Department of Industrial Chemistry, Faculty of Science, Kaduna State University, P.M.B 2232 Kaduna, Nigeria

Abstract

This study explores the potential of titanium oxide impregnated on calcium oxide (CaO-TiO2) as catalyst in transesterification of vegetable palm oil (VPO) to produce biodiesel. The biodiesel yield increased with catalyst calcination temperature and reaction time, and the usage of CaO-TiO2 led to higher biodiesel production when compared to reaction catalyzed by CaO. Biodiesel yield of 93.33% was recorded when CaO-TiO2 was used at optimized reaction conditions. Catalyst characterizations showed that addition of TiO2 to CaO improved the catalytic property by increasing the surface area and strength of basic sites, hence increased the catalytic performance of TiO2-CaO. This study demonstrates the potential of CaO-TiO2 to convert VPO into biodiesel, and the potential of the catalyst in conversion of waste cooking oil into renewable fuel will be studied.

Keywords


1.     Wong, S.L., Ngadi, N., Abdullah, T.A.T. and Inuwa, I.M., "Recent advances of feed-in tariff in malaysia", Renewable & Sustainable Energy Reviews,  Vol. 41, (2015), 42-52.
2.     Hadiyanto, H., Widayat, W. and Duma, A., "Ultrasoun assiste in situ esterification of rubber seeds oil for bioiesel production", International Journal of Engineering-Transactions C: Aspects,  Vol. 29, No. 12, (2016), 1635.
3.     Pazouki, M., Zamani, F. and Khalili, M., "Development of clay foam ceramic as a support for fungi immobilization for biodiesel production", International Journal of Engineering-Transactions B: Applications,  Vol. 27, No. 11, (2014), 1691-1696.
4.     Jafarmadar, S. and Pashae, J., "Experimental study of the effect of castor oil biodiesel fuel on performance and emissions of turbocharged di diesel", International Journal of Engineering-Transactions B: Applications,  Vol. 26, No. 8, (2013), 905.
5.     Hosseini, S.E. and Wahid, M.A., "Necessity of biodiesel utilization as a source of renewable energy in malaysia", Renewable & Sustainable Energy Reviews,  Vol. 16, No. 8, (2012), 5732-5740.
6.     Atabani, A.E., Silitonga, A.S., Badruddin, I.A., Mahlia, T.M.I., Masjuki, H.H. and Mekhilef, S., "A comprehensive review on biodiesel as an alternative energy resource and its characteristics", Renewable & Sustainable Energy Reviews,  Vol. 16, No. 4, (2012), 2070-2093.
7.     Yaakob, Z., Mohammad, M., Alherbawi, M., Alam, Z. and Sopian, K., "Overview of the production of biodiesel from waste cooking oil", Renewable & Sustainable Energy Reviews,  Vol. 18, (2013), 184-193.
8.     Lam, M.K., Lee, K.T. and Mohamed, A.R., "Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review", Biotechnology Advances,  Vol. 28, No. 4, (2010), 500-518.
9.     Zabeti, M., Wan Daud, W.M.A. and Aroua, M.K., "Activity of solid catalysts for biodiesel production: A review", Fuel Processing Technology,  Vol. 90, No. 6, (2009), 770-777.
10.   Anonymous. Calcium oxide.  2018  [cited 08/01/2018; Available from: https://toxnet.nlm.nih.gov/cgi-bin/sis/search/a?dbs+hsdb:@term+@DOCNO+1615.
11.   Yoo, S.J., Lee, H.S., Veriansyah, B., Kim, J., Kim, J.D. and Lee, Y.W., "Synthesis of biodiesel from rapeseed oil using supercritical methanol with metal oxide catalysts", Bioresource Technology,  Vol. 101, No. 22, (2010), 8686-8689.
12.   Feyzi, M. and Shahbazi, E., "Catalytic performance and characterization of cs-ca/sio2-tio2 nanocatalysts for biodiesel production", Journal of Molecular Catalysis a-Chemical,  Vol. 404, (2015), 131-138.
13.   Madhuvilakku, R. and Piraman, S., "Biodiesel synthesis by tio2-zno mixed oxide nanocatalyst catalyzed palm oil transesterification process", Bioresource Technology,  Vol. 150, (2013), 55-59.
14.   Mohamad, M., Ngadi, N., Wong, S.L., Jusoh, M. and Yahya, N.Y., "Prediction of biodiesel yield during transesterification process using response surface methodology", Fuel,  Vol. 190, (2017), 104-112.
15.   Hu, S.Y., Wang, Y. and Han, H.Y., "Utilization of waste freshwater mussel shell as an economic catalyst for biodiesel production", Biomass & Bioenergy,  Vol. 35, No. 8, (2011), 3627-3635.
16.   Wong, S., Ngadi, N., Abdullah, T.A.T. and Inuwa, I.M., "Catalytic cracking of ldpe dissolved in benzene using nickel-impregnated zeolites", Industrial & Engineering Chemistry Research,  Vol. 55, No. 9, (2016), 2543-2555.
17.   Rodriguez, D.F. and Perillo, P.M., "Tio2 nanopores with high sensitivity to ultraviolet light", Optical Materials,  Vol. 42, (2015), 52-55.
18.   Yusup, S. and Khan, M.A., "Base catalyzed transesterification of acid treated vegetable oil blend for biodiesel production", Biomass & Bioenergy,  Vol. 34, No. 10, (2010), 1500-1504.
19.   Sohaimi, K., Ngadi, N., Mat, H., Inuwa, I. and Wong, S., "Synthesis, characterization and application of textile sludge biochars for oil removal", Journal of Environmental Chemical Engineering,  Vol. 5, No. 2, (2017), 1415-1422.
20.   Tang, Y., Chen, G., Zhang, J. and Lu, Y., "Highly active cao for the transesterification to biodiesel production from rapeseed oil", Bulletin of the Chemical Society of Ethiopia,  Vol. 25, No. 1, (2011), 37-42.
21.   Takase, M., Chen, Y., Liu, H., Zhao, T., Yang, L. and Wu, X., "Biodiesel production from non-edible silybum marianum oil using heterogeneous solid base catalyst under ultrasonication", Ultrasonics Sonochemistry,  Vol. 21, No. 5, (2014), 1752-1762.
22.   Farooq, M., Ramli, A. and Naeem, A., "Biodiesel production from low ffa waste cooking oil using heterogeneous catalyst derived from chicken bones", Renewable Energy,  Vol. 76, (2015), 362-368.
23.   Mohamad, M. and Ngadi, N., "Effect of tio2 mixed cao catalyst in palm oil transesterification", Applied Mechanics and Materials,  Vol. 695, (2014), 319.
24.   Boro, J., Thakur, A.J. and Deka, D., "Solid oxide derived from waste shells of turbonilla striatula as a renewable catalyst for biodiesel production", Fuel Processing Technology,  Vol. 92, No. 10, (2011), 2061-2067.
25.   Witoon, T., Bumrungsalee, S., Vathavanichkul, P., Palitsakun, S., Saisriyoot, M. and Faungnawakij, K., "Biodiesel production from transesterification of palm oil with methanol over cao supported on bimodal meso-macroporous silica catalyst", Bioresource Technology,  Vol. 156, (2014), 329-334.
26.   Tang, S.K., Wang, L.P., Zhang, Y., Li, S.F., Tian, S.J. and Wang, B.Y., "Study on preparation of ca/al/fe3o4 magnetic composite solid catalyst and its application in biodiesel transesterification", Fuel Processing Technology,  Vol. 95, (2012), 84-89.
27.   Omar, W.N.N.W. and Amin, N.A.S., "Biodiesel production from waste cooking oil over alkaline modified zirconia catalyst", Fuel Processing Technology,  Vol. 92, No. 12, (2011), 2397-2405.
28.   Boro, J., Konwar, L.J., Thakur, A.J. and Deka, D., "Ba doped cao derived from waste shells of tstriatula (ts-cao) as heterogeneous catalyst for biodiesel production", Fuel,  Vol. 129, (2014), 182-187.
29.   Taufiq-Yap, Y.H., Lee, H.V., Hussein, M.Z. and Yunus, R., "Calcium-based mixed oxide catalysts for methanolysis of jatropha curcas oil to biodiesel", Biomass & Bioenergy,  Vol. 35, No. 2, (2011), 827-834.
30.   Zhang, Y., Zhao, Z., Chen, J., Cheng, L., Chang, J., Sheng, W., Hu, C. and Cao, S., "C-doped hollow tio2 spheres: In situ synthesis, controlled shell thickness, and superior visible-light photocatalytic activity", Applied Catalysis B: Environmental,  Vol. 165, (2015), 715-722.