International Journal of Engineering

International Journal of Engineering

Catalytic Conversion of Heavy Oil Using Molybdenum Based Water-soluble Catalyst

Document Type : Special Issue on FPP

Authors
1 Development and Operation of Oil and Gas Fields, Saint-Petersburg Mining University, Saint-Petersburg, Russia
2 Lukoil-Engineering LLC, Perm, Russia
Abstract
The growing global trend of putting heavy oil fields into development is a complex task that requires updating previously unprofitable approaches. One of such areas is cyclic steam stimulation of wells to stimulate the production of high-viscous and super-viscous oils. An increase in well flow rates and the depletion of reserves, a decrease in the time and financial costs of well servicing and workover can be achieved by combining thermal and chemical methods of inflow stimulation. This approach has proven itself successfully in the catalytic in-situ upgrading of oil. Within the framework of this article, a series of laboratory experiments were performed to confirm the effectiveness of ammonium molybdate as a water-soluble precursor of an aquathermolysis catalyst for upgrading super-viscous oil from one of the fields of the Timan-Pechora oil and gas province. The decrease in oil viscosity relative to the non-catalytic effect was 24%, which was also confirmed by the results of the SARA-analysis of oil: a decrease in the amount of asphaltenes by 15.9%, an increase in the amount of saturated and aromatic hydrocarbons by 3% and 4.6%, respectively. Based on a simple numerical model was predicted an increase in oil flow rate with a catalytic effect relative to a non-catalytic effect by 23%. The results obtained indicate the potential for using this catalyst precursor in field conditions.

Graphical Abstract

Catalytic Conversion of Heavy Oil Using Molybdenum Based Water-soluble Catalyst
Keywords

Subjects


  1. Belsky A, Starshaia V, Shklyarsky J. Enhanced Energy Efficiency of Oil Production Using Photovoltaic Installation. International Journal of Engineering, Transactions A: Basics. 2025;38(01):194-204. 10.5829/ije.2025.38.01a.18
  2. Podoprigora D, Sabukevich V, Korobov G, Nguen V. Justification of developed system measures to increase productivity of wells in eastern part of pechora sea oil field. International Journal of Engineering, Transactions B: Applications. 2024;37(11):2303-13. 10.5829/ije.2024.37.11b.1
  3. Korobov G, Vorontsov A, Buslaev G. Influence of Inhibitors Based on Surfactants on Processes of Hydrates and Asphalt-Resin-Paraffin Deposits Formation: Experimental Studies. International Journal of Engineering, Transactions A: Basics. 2025;38(10):2220-30. 10.5829/ije.2025.38.10a.02
  4. Bosikov II, Klyuev RV, Mayer АV. Comprehensive assessment of hydraulic fracturing technology efficiency for well construction during hydrocarbon production. Записки Горного института. 2022;258:1006-13. 10.31897/PMI.2022.98
  5. Drozdov NA. Filtration studies on cores and sand packed tubes from the Urengoy field for determining the efficiency of simultaneous water and gas injection on formation when extracting condensate from low-pressure reservoirs and oil from oil rims. Записки Горного института. 2022;257:783-94. 10.31897/PMI.2022.71
  6. Nurgalieva KS, Saychenko LA, Riazi M. Improving the efficiency of oil and gas wells complicated by the formation of Asphalt–Resin–Paraffin deposits. Energies. 2021;14(20):6673. 10.3390/en14206673
  7. Petrakov D, Loseva A, Jafarpour H, Penkov G. Experimental evaluation of effective chemical composition on reservoir quality of bottomhole zone of low permeability terrigenous reservoirs. International Journal of Engineering Transactions B: Applications. 2024;37(8):1547-55. 10.5829/ije.2024.37.08b.08
  8. Tananykhin D, Struchkov I, Khormali A, Roschin P. Investigation of the influences of asphaltene deposition on oilfield development using reservoir simulation. Petroleum Exploration and Development. 2022;49(5):1138-49. 10.1016/S1876-3804(22)60338-0
  9. Raupov I, Rogachev M, Sytnik J. Overview of Modern Methods and Technologies for the Well Production of High-and Extra-High-Viscous Oil. Energies. 2025;18(6):1498. 10.3390/en18061498
  10. Malarev V, Kopteva A, Koptev V, Gotsul Y. Improvement of efficiency of steam-thermal treatment of high-viscous oil formations using downhole electric steam generators. Journal of Ecological Engineering. 2021;22(2):17-24. 10.12911/22998993/130630
  11. Yang S, Huang S, Jiang Q, Jiang G, Zhou X, Yu C. An innovative in situ solvent generation enhanced SAGD technique: Mechanism analysis based on numerical simulation. Fuel. 2024;364:131020. 10.1016/j.fuel.2024.131020
  12. Durkin S, Morozyuk O, Kalinin S, Ruzin L, Menshikova I. Substantiation of the optimal strategies of steam injection for enhanced oil recovery at the Yaregskoye field based on physical and mathematical modeling (Russian). Oil Industry Journal. 2018;2018(01):58-61. 10.24887/0028-2448-2018-1-58-61
  13. Kondrasheva NK RV, Nazarenko MY, Gabdulkhakov RR. . Influence of parameters of delayed asphalt coking process on yield and quality of liquid and solid-phase products. Journal of Mining Institute. 2020;241(1):97-104. 10.31897/pmi.2020.1.97
  14. Aliev FA, Mukhamatdinov II, Sitnov SA, Ziganshina MR, Onishchenko YV, Sharifullin AV, et al. In-situ heavy oil aquathermolysis in the presence of nanodispersed catalysts based on transition metals. Processes. 2021;9(1):127. 10.3390/pr9010127
  15. Alieva F, Vakhina A, Mirzaeva O, Dengaevb A, Safiullinac E, Efremenko D, et al. Utilizing an Oil-soluble Iron and Sodium-based Catalyst for Catalytic Hydrogenation of Carbon Dioxide in Heavy Oil. International Journal of Engineering, Transactions B: Applications. 2025;38(2):321-29. 10.5829/ije.2025.38.02b.06
  16. Vakhin A, Mukhamatdinov I, Sitnov S, Mukhamatdinova R, Simakov I, Nikitina E, et al. Catalytic activity of nickel and iron sulfides in the degradation of resins and asphaltenes of high-viscosity oil in the presence of carbonate rock under hydrothermal conditions. Kinetics and Catalysis. 2022;63(5):569-76. 10.31857/S0453881122050148
  17. Varfolomeev MA, Yuan C, Ancheyta J. Catalytic In-Situ Upgrading of Heavy and Extra-Heavy Crude Oils: John Wiley & Sons; 2023.
  18. Panariti N, Del Bianco A, Del Piero G, Marchionna M. Petroleum residue upgrading with dispersed catalysts: Part 1. Catalysts activity and selectivity. Applied Catalysis A: General. 2000;204(2):203-13. 10.1016/S0926-860X(00)00531-7
  19. Al-Mishaal OF, Suwaid MA, Al-Muntaser AA, Khelkhal MA, Varfolomeev MA, Djimasbe R, et al. Octahedral cluster complex of molybdenum as oil-soluble catalyst for improving in situ upgrading of heavy crude oil: Synthesis and application. Catalysts. 2022;12(10):1125. 10.3390/catal12101125
  20. Razavian M, Fatemi S. Catalytic evaluation of metal azolate framework-6 in pristine and metal doped modes in upgrading heavy residual fuel oil. Journal of Analytical and Applied Pyrolysis. 2021;156:105093. 10.1016/j.jaap.2021.105093
  21. Felix G, Tirado A, Varfolomeev MA, Al-muntaser A, Suwaid M, Yuan C, et al. Chemical and structural changes of resins during the catalytic and non-catalytic aquathermolysis of heavy crude oils. Geoenergy Science and Engineering. 2023;230:212242. 10.1016/j.geoen.2023.212242
  22. Deng Q LY, Chen G, Yan J, Zhang J, Meng M, Qu C, Jeje A. Water-soluble metal complexes as catalysts for low-temperature aquathermolysis of heavy oil in the presence of methanol. Neftekhimia. 2018;58(4):522-6. 10.1134/S0028242118040238
  23. Zhou Z, Li X, Gao K, Nan J, Xiao H, Lu Y, et al. A review on the reaction mechanism of heavy oil catalytic aquathermolysis: Carbocationic reactions or free radical reactions? Journal of Analytical and Applied Pyrolysis. 2025;186:106923. 10.1016/j.jaap.2024.106923
  24. Wu C, Lei G, Yao C, Jia X, editors. In situ upgrading extra-heavy oil by catalytic aquathermolysis treatment using a new catalyst based anamphiphilic molybdenum chelate. SPE International Oil and Gas Conference and Exhibition in China; 2010: SPE. 10.2118/130333-MS
  25. Chuan W, Guang-Lun L, Chuan-Jin Y, Ke-Ji S, Yan-bin C. Mechanism for reducing the viscosity of extra-heavy oil by aquathermolysis with an amphiphilic catalyst. Journal of Fuel Chemistry and Technology. 2010;38(6):684-90. 10.1016/S1872-5813(11)60004-2
  26. Tumanyan BP PN, Kayukova GP, Nurgaliev DK, Foss LE, Romanov GV. . Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation. Russian Chemical Reviews. 2015;84(11):1145. 10.1070/RCR4500
  27. Zhao F, Liu Y, Lu N, Xu T, Zhu G, Wang K. A review on upgrading and viscosity reduction of heavy oil and bitumen by underground catalytic cracking. Energy Reports. 2021;7:4249-72. https://doi.org/10.1016/j.egyr.2021.06.094
  28. Liu R-Q, Zhang L-Q, Pan H-D, Wang Y-Y, Li J-Y, Wang X-W, et al. Study on the in situ desulfurization and viscosity reduction of heavy oil over MoO3–ZrO2/HZSM-5 catalyst. Petroleum Science. 2023;20(6):3887-96. 10.1016/j.petsci.2023.08.005
  29. Tajik S, Shahrabadi A, Rashidi A. Silica-graphene nanohybrid supported MoS2 nanocatalyst for hydrogenation reaction and upgrading heavy oil. Journal of Petroleum Science and Engineering. 2019;177:822-8. 10.1016/j.petrol.2019.02.085
  30. Cai Z, Ding Y, Zhang J, Yu P, Ma Y, Cao Y, et al. In situ generation of dispersed MoS2 catalysts from oil-soluble Mo-based ionic liquids for highly effective biolipids hydrodeoxygenation. Journal of Catalysis. 2023;423:50-61. 10.1016/j.jcat.2023.04.022
  31. Qu X, Zhou G, Lu Y, Li S, Zhang L, Wang J, et al. Catalytic aquathermolysis of Mackay River bitumen with different types of Mo-based catalysts. Fuel. 2022;326:125134. 10.1016/j.fuel.2022.125134
  32. Wang J, Tang X, Li J, Guo E, Guan W, Jiang Y. Quartz sand proppant loaded with Ni and Mo for in-situ aquathermolysis of heavy oil. Fuel. 2021;306:121653. 10.1016/j.fuel.2021.121653
  33. Khoshooei MA, Vitale G, Carbognani L, Scott CE, Pereira-Almao P. Molybdenum carbide nanocatalyst for activation of water and hydrogen towards upgrading of low-quality hydrocarbons. Fuel. 2022;322:124291. 10.1016/j.fuel.2022.124291
  34. Wang J, Gao K, Zhong Y, Nan J, Li X, Zhao H, et al. In-situ formation of molybdenum disulfide nanoparticle and its catalytic performance in heavy oil long-term aquathermolysis. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2025;707:135861. 10.1016/j.colsurfa.2024.135861
  35. Wang Y, Lin R, Zhang L, Han X, Li J, Huang C, et al. ZrO2-MoO3/modified lotus stem biochar catalysts for catalytic aquathermolysis of heavy oil at low-temperature. Fuel. 2024;357:129597. 10.1016/j.fuel.2023.129597
  36. Kiekbaev A VA. Aquathermolysis of high-viscosity oil of the Yaregsky field in the presence of components of rock-forming minerals. Oil & Gas Chemistry. 2021;1-2:37-42. 10.24412/2310-8266-2021-1-2-37-42
  37. Alonso JPP, Djimasbe R, Zairov R, Yuan C, Al-Muntaser AA, Stepanov A, et al. Use of nickel oxide catalysts (bunsenites) for in-situ hydrothermal upgrading process of heavy oil. Nanomaterials. 2023;13(8):1351. https://doi.org/10.3390/nano13081351
  38. Katnov VE, Trubitsina SA, Kayumov AA, Aliev FA, Nazimov NA, Dengaev AV, et al. Influence of sodium metal nanoparticles on the efficiency of heavy oil aquathermolysis. Catalysts. 2023;13(3):609. 10.3390/catal13030609
  39. Baygildin E SS, Vakhin A, Sharifullin A, Amerkhanov M, Garifullina E. . Aquathermolysis of heavy oil in the presence of bimetallic catalyst that form in-situ from the mixture of oil-soluble iron and cobalt precursors. Georesources. 2019;21(3):62-7. 10.18599/grs.2019.3.62-67
  40. Kadieva MK, Khadzhiev S, Kadiev KM, Gyul’Maliev A, Yakovenko T. The formation of nanosized molybdenum oxide particles in a hydrocarbon medium. Petroleum Chemistry. 2011;51(1):16-23. 10.1134/S0965544111010051
  41. Li Y, Zhang S, Wang Y, Qi G, Yu T, Xin X, et al. Oil-soluble exogenous catalysts and reservoir minerals synergistically catalyze the aquathermolysis of heavy oil. Molecules. 2023;28(19):6766. https://doi.org/10.3390/molecules28196766