International Journal of Engineering

International Journal of Engineering

Influence of ZrB2/SiC Hybrid Particles on Microstructure and Creep Resistance of AZ31Magnesium Alloy Matrix Composite

Document Type : Original Article

Authors
1 Department of Mining and Metallurgical Engineering, Yazd University, Yazd, Iran
2 Department of Material Science and Engineering, Sharif University of Technology, Tehran, Iran
3 Faculty of Materials Science and Engineering, Department of Engineering, Imam Hossein University Tehran, Iran
Abstract
Magnesium alloys have been attractive to engineers due to their high strength-to-weight ratio, leading to their widespread use in recent years. However, their poor creep resistance, particularly at high temperatures, has limited their applications. Reinforcing the magnesium matrix with ceramic particles could significantly improve creep properties. In this research, ZrB2 and SiC microparticles were separately milled for 6 hours at 350 rpm under an argon atmosphere, and powders were mixed and milled for 2 hours at the same condition to achieve a homogeneous hybrid powder. The hybrid particles were added to the AZ31 magnesium alloy in various amounts via the stir-casting method, to produce hybridcomposites. The microstructure of specimens has been characterized using optical microscopy (OM), scanning electron microscopy (SEM), X-ray analysis (XRD), and energy-dispersive X-ray spectroscopy (EDX). The results indicated that the AZ31/1.5vol% ZrB2-0.5vol% SiC hybridcomposite possessed the finest grains with uniform distribution of reinforcements and the intermetallic β-Mg17Al12 phase. Hardness and creep tests were performed to evaluate the creep resistance of the hybridcomposites. While AZ31/2vol% SiC showed the highest hardness, the AZ31/1.5vol% ZrB2-0.5vol% SiC hybridcomposite demonstrated the best creep behavior.

Graphical Abstract

Influence of ZrB2/SiC Hybrid Particles on Microstructure and Creep Resistance of AZ31Magnesium Alloy Matrix Composite
Keywords

Subjects


  1. Bharathi P, Sampath Kumar T. Latest research and developments of ceramic reinforced magnesium matrix composites—A comprehensive review. Proceedings of the Institution of Mechanical Engineers, Part E: Journal of Process Mechanical Engineering. 2023;237(3):1014-35. https://doi.org/10.1177/09544089221126044
  2. Fan S, Wang X, Wang GG, Weiler JP. Applications of High-Pressure Die-Casting (HPDC) Magnesium Alloys in Industry. Magnesium Alloys-Processing, Potential and Applications: IntechOpen; 2023.
  3. Mitra A, Mandal SK, Rai RN. Synthesis and characterisation of magnesium-based nano-composite–A review. Proceedings of the Institution of Mechanical Engineers, Part E: Journal of Process Mechanical Engineering. 2024;238(6):2994-3008. https://doi.org/10.1177/09544089231167758
  4. Zhang T, Wang W, Liu J, Wang L, Tang Y, Wang K. A review on magnesium alloys for biomedical applications. Frontiers in bioengineering and biotechnology. 2022;10:953344. https://doi.org/10.3389/fbioe.2022.953344
  5. Maraki M, Tagimalek H, Azargoman M, Khatami H, Mahmoodi M. Experimental investigation and statistical modeling of the effective parameters in charpy impact test on AZ31 magnesium alloy with v-shape groove using taguchi method. International Journal of Engineering, Transactions C: Aspects. 2020;33(12):2521-9. 10.5829/ije.2020.33.12c.13
  6. Amalan P, Sivaram N. A state-of-the-art review on magnesium-based composite materials. Adv Mater Process Technol. 2022;9(3):760-78. https://doi.org/10.1080/2374068X.2022.2096835
  7. Agha AFH, Bani MAN, Hosseinpour GM, Nami B. The effect of rapid deformation process to improve creep and tensile resistance of AZ91 magnesium alloy plates. International Journal of Engineering Transactions A: Basics. 2020;33(10):2039-46. 10.5829/ije.2020.33.10a.22
  8. Chen T, Hu S, Li S, Huo Q. Uncovering the unexpected changes of creep properties in AZ-series Mg alloys. Materials Science and Engineering: A. 2022;857:144056. https://doi.org/10.1016/j.msea.2022.144056
  9. Zhang S, Du H, Yao Z, Liu Z, Zhu Y, Shuai L, et al. Superior high temperature creep resistance of a cast Al–Mg–Ca-Sc alloy with multi-scale hierarchical microstructures. Materials Science and Engineering: A. 2022;850:143533. https://doi.org/10.1016/j.msea.2022.143533
  10. Hu P, Liu K, Pan L, Chen X-G. Effect of Mg microalloying on elevated-temperature creep resistance of Al–Cu 224 cast alloys. Materials Science and Engineering: A. 2022;851:143649. https://doi.org/10.1016/j.msea.2022.143649
  11. Zhang D, Zhang J, Zhang Y, Li B, Zhao Y, Che C, et al. Creep behavior and microstructure evolution of heat-resistant Mg-Sm-Yb-Zn-Zr alloy. Materials Science and Engineering: A. 2022;848:143358. https://doi.org/10.1016/j.msea.2022.143358
  12. Subramani M, Huang S-J, Borodianskiy K. Effect of SiC nanoparticles on AZ31 magnesium alloy. Materials. 2022;15(3):1004. https://doi.org/10.3390/ma15031004
  13. Yang Q, Yan Z, Lv S, Guan K, Qiu X. Abnormal creep stress exponents in a high-pressure die casting Mg–Al− RE alloy. Materials Science and Engineering: A. 2022;831:142203. https://doi.org/10.1016/j.msea.2021.142203
  14. Kiarasi F, Babaei M, Omidi Bidgoli M, Reza Kashyzadeh K, Asemi K. Mechanical characterization and creep strengthening of AZ91 magnesium alloy by addition of yttrium oxide nanoparticles. Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications. 2022;236(8):1489-500. https://doi.org/10.1177/14644207211073499
  15. Safari A, Mahmudi R. High Temperature Mechanical Properties of an Extruded Mg–TiO2 Nano‐Composite. Advanced Engineering Materials. 2015;17(11):1639-44. https://doi.org/10.1002/adem.201500132
  16. Sklenička V, Svoboda M, Pahutova M, Kuchařová K, Langdon T. Microstructural processes in creep of an AZ 91 magnesium-based composite and its matrix alloy. Materials Science and Engineering: A. 2001;319:741-5. https://doi.org/10.1016/S0921-5093(01)01023-1
  17. Ferkel H, Mordike B. Magnesium strengthened by SiC nanoparticles. Materials Science and Engineering: A. 2001;298(1-2):193-9. https://doi.org/10.1016/S0921-5093(00)01283-1
  18. Ren Z, Zhang X, Sui L, Zhang T, Pang L, Jin J. Fabrication of ZrB2 particles reinforced AZ31 magnesium matrix composite by powder metallurgy and subsequent hot extrusion. Materials Research Innovations. 2010;14(3):206-9. https://doi.org/10.1179/143307510X12719005364422
  19. Guan R, Zhao Z, Huang H, Zhang Q, Liu C. Mathematic model of solid fraction during rheo-casting by the cooling sloping plate process. Acta Metallurgica Sinica(English Letters). 2012;25(1):81-8. 10.11890/1006-7191-121-81
  20. Veeranjaneyulu I, Chittaranjan Das V, Karumuri S. Enhancing the Mechanical Properties of AZ31D Alloy by Reinforcing Nanosilicon Carbide/Graphite. Journal of Nanomaterials. 2023;2023(1):6553200. https://doi.org/10.1155/2023/6553200
  21. Veeranjaneyulu I, Chittaranjan Das V, Karumuri S. Investigation of Mechanical Properties and Microstructure of AZ31‐SiC‐Graphite Hybrid Nanocomposites Fabricated by Bottom Pouring‐Type Stir Casting Machines. Advances in Materials Science and Engineering. 2023;2023(1):3402348. https://doi.org/10.1155/2023/3402348
  22. Paramsothy M, Gupta M. Critically designing today’s melt processed bulk magnesium alloys using boron rich nanoparticles. Materials & Design. 2015;66:557-65. https://doi.org/10.1016/j.matdes.2014.03.015
  23. Sahu MK, Sahu RK. Fabrication of aluminum matrix composites by stir casting technique and stirring process parameters optimization. Advanced casting technologies. 2018:111-23. 10.5772/intechopen.73485
  24. Jurwall V, Pandey A, Sharma A, editors. Fabrication of Nano Hybrid Metal Matrix Composites through Stir Casting Route: A Review. IOP Conference Series: Materials Science and Engineering; 2018: IOP Publishing. 10.1088/1757-899X/377/1/012142
  25. Kandpal BC, Kumar J, Singh H. Manufacturing and technological challenges in Stir casting of metal matrix composites–A Review. Materials Today: Proceedings. 2018;5(1):5-10. https://doi.org/10.1016/j.matpr.2017.11.046
  26. Mistry JM, Gohil PP. Research review of diversified reinforcement on aluminum metal matrix composites: fabrication processes and mechanical characterization. Science and Engineering of Composite Materials. 2018;25(4):633-47. https://doi.org/10.1515/secm-2016-0278
  27. Saravanan C, Subramanian K, Krishnan VA, Narayanan RS. Effect of particulate reinforced aluminium metal matrix composite–a review. Mechanics and Mechanical Engineering. 2015;19(1):23-30.
  28. Sandra V, Gajic S, Stojanovic B, Vencl A. Tribological properties of aluminium matrix nanocomposites. Applied Engineering Letters, 1(3), 2016: 72-79.
  29. Galán CA, Ortiz AL, Guiberteau F, Shaw LL. High‐Energy Ball Milling of ZrB2 in the Presence of Graphite. Journal of the American Ceramic Society. 2010;93(10):3072-5. https://doi.org/10.1111/j.1551-2916.2010.04051.x
  30. Döndaş DO. Co-synthesis of zirconium boride/silicide/oxide composite powders by magnesiothermic reduction. Journal of Boron.7(4):552-9. https://doi.org/10.30728/boron.1177551
  31. López-Arenal J, Moshtaghioun BM, Cumbrera FL, Gómez-García D, Ortiz AL. Powder-metallurgy fabrication of ZrB2–hardened Zr3Al2 intermetallic composites by high-energy ball-milling and reactive spark-plasma sintering. Journal of Materials Research and Technology. 2022;21:617-26. 10.1016/j.jmrt.2022.09.071
  32. Li C, Li W, Zhang X, Du L, Sheng H. Predicted stable electrides in Mg–Al systems under high pressure. Physical Chemistry Chemical Physics. 2022;24(20):12260-6. https://doi.org/10.1039/D2CP00981A
  33. Su Q, Wang R, Yu H, Li H, Zhou J, Wang D, et al. The effect of submicron SiC particles on the thermal stability of nanocrystalline AZ91 alloy. Journal of Materials Research and Technology. 2023;22:519-30. https://doi.org/10.1016/j.jmrt.2022.11.147
  34. Mattli MR, Matli PR, Khan A, Abdelatty RH, Yusuf M, Ashraf AA, et al. Study of microstructural and mechanical properties of Al/SiC/TiO2 hybrid nanocomposites developed by microwave sintering. Crystals. 2021;11(9):1078. https://doi.org/10.3390/cryst11091078
  35. Chen Q, Zhang L, Tang S, Liang C, Ma Y, Liu W. Examination of dendritic growth and microsegregation during solidification of Al–Li binary alloy using the phase-field simulation coupling CALPHAD data. Calphad. 2021;74:102271. https://doi.org/10.1016/j.calphad.2021.102271
  36. Fang C, Fan Z. Atomic ordering at the liquid-Al/MgAl2O4 interfaces from ab initio molecular dynamics simulations. Metallurgical and Materials Transactions A. 2020;51(12):6318-26. 10.1007/s11661-020-05994-9
  37. Ridgeway CD, Gu C, Luo AA. Predicting primary dendrite arm spacing in Al–Si–Mg alloys: effect of Mg alloying. Journal of Materials Science. 2019;54(13):9907-20. 10.1007/s10853-019-03558-w
  38. Yu A, Yang X, Guo H, Yu K, Sun X, Li Z. Numerical Simulation and Experimental Validation of Nondendritic Structure Formation in Magnesium Alloy Under Oscillation and Ultrasonic Vibration (vol 50, pg 2319, 2019). METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE. 2019;50(6):3126-. 10.1007/s11663-019-01694-x
  39. Dong B-X, Li Q, Yang H-Y, Liu T-S, Qiu F, Shu S-L, et al. Synergistic optimization in solidification microstructure and mechanical performance of novel (TiCxNy− TiB2) p/Al nanocomposites: design, tuning and mechanism. Composites Part A: Applied Science and Manufacturing. 2022;155:106843. 10.1016/j.compositesa.2022.106843
  40. Liu S, Zhang X, Peng H-L, Han X, Yang H-Y, Li T-T, et al. In situ nanocrystals manipulate solidification behavior and microstructures of hypereutectic Al-Si alloys by Zr-based amorphous alloys. Journal of Materials Research and Technology. 2020;9(3):4644-54. 10.1016/j.jmrt.2020.02.091
  41. Song X-Y, Wang Y-J, Zhang J-X, Du D-A, Xu J-G, Peng F, et al. Solidification microstructure manipulation mechanism of hypoeutectic and hypereutectic Al–Si alloys controlled by trace in-situ nano-Fe2B and nano-Fe3Si. Journal of Materials Research and Technology. 2022;21:3856-69. 10.1016/j.jmrt.2022.10.142
  42. Xie J-F, Liu T-S, Li Q, Li Q-Y, Xu Z-H, Qiu F, et al. Nanoparticulate dispersion, microstructure refinement and strengthening mechanisms in Ni-coated SiCp/Al-Cu nanocomposites. Materials Science and Engineering: A. 2019;762:138092. 10.1016/j.msea.2019.138092
  43. Zhao K, Gao T, Yang H, Hu K, Liu G, Sun Q, et al. Enhanced grain refinement and mechanical properties of a high–strength Al–Zn–Mg–Cu–Zr alloy induced by TiC nano–particles. Materials Science and Engineering: A. 2021;806:140852. 10.1016/j.msea.2021.140852
  44. Ayyanar S, Gnanavelbabu A, Rajkumar K, Loganathan P, Vishal K. Investigation on microstructure and tribological performance of zirconium boride reinforced AZ91D magnesium alloy: effect of processing routes. Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science. 2023;237(3):692-707. https://doi.org/10.1177/09544062221125058
  45. Viswanath A, Dieringa H, Kumar KA, Pillai U, Pai B. Investigation on mechanical properties and creep behavior of stir cast AZ91-SiCp composites. Journal of Magnesium and alloys. 2015;3(1):16-22. 10.1016/j.jma.2015.01.001
  46. Athul KR, Pillai UTS, Srinivasan A, Pai BC. A review of different creep mechanisms in Mg alloys based on stress exponent and activation energy. Advanced Engineering Materials. 2016;18(5):770-94. 10.1002/adem.201500393
  47. Pahutova M, Sklenicka V, Kucharova K, Svoboda M. Creep resistance in magnesium alloys and their composites. International Journal of Materials and Product Technology. 2003;18(1-3):116-40. 10.1504/IJMPT.2003.003588
  48. Mukherjee AK, Bird JE, Dorn JE. Experimental correlations for high-temperature creep. 1968.
  49. Kondori B, Mahmudi R. Impression creep characteristics of a cast Mg alloy. Metallurgical and Materials Transactions A. 2009;40:2007-15. 10.1007/s11661-009-9867-4
  50. Ishimatsu N, Terada Y, Sato T, Ohori K. Creep characteristics of a diecast AM50 magnesium alloy. Metallurgical and Materials Transactions A. 2006;37:243-8. 10.1007/S11661-006-0169-9
  51. Kabirian F, Mahmudi R. Impression creep behavior of a cast AZ91 magnesium alloy. Metallurgical and Materials Transactions A. 2009;40:116-27. 10.1007/s11661-008-9699-7
  52. Wei S, Chen Y, Tang Y, Zhang X, Liu M, Xiao S, et al. Compressive creep behavior of Mg–Sn–La alloys. Materials Science and Engineering: A. 2009;508(1-2):59-63. https://doi.org/10.1016/j.msea.2008.12.049
  53. Zheng L, Nie H, Liang W, Wang H, Wang Y. Effect of pre-homogenizing treatment on microstructure and mechanical properties of hot-rolled AZ91 magnesium alloys. Journal of Magnesium and Alloys. 2016;4(2):115-22. https://doi.org/10.1016/j.jma.2016.04.002
  54. Che C, Cai Z, Yang X, Cheng L, Du Y. The effect of co-addition of Si, Ca and RE on microstructure and tensile properties of as-extruded AZ91 alloy. Materials Science and Engineering: A. 2017;705:282-90. https://doi.org/10.1016/j.msea.2017.08.026
  55. Luo A, Pekguleryuz M. Cast magnesium alloys for elevated temperature applications. Journal of materials science. 1994;29:5259-71. https://doi.org/10.1007/BF01171534
  56. Evans H, Knowles G. Threshold stress for creep in dispersion-strengthened alloys. Metal Science. 1980;14(7):262-6. https://doi.org/10.1179/030634580790426382
  57. Clauer A, Hansen N. High temperature strength of oxide dispersion strengthened aluminium. Acta Metallurgica. 1984;32(2):269-78. https://doi.org/10.1016/0001-6160(84)90055-5
  58. Emley EF. Principles of magnesium technology. (No Title). 1966. 10.5829/ije.2020.33.08b.16
  59. Azadi M, Aroo H. Temperature effect on creep and fracture behaviors of nano-SiO2-composite and alsi12cu3ni2mgfe aluminum alloy. International Journal of Engineering. 2020;33(8):1579-89. 10.1080/0371750X.2023.2189621
  60. Ji Z, Liao N, Li Y, Zhu T, Nath M, Yang Z. Microstructure and Thermal Shock Resistance of Zr7/8Ti1/8B2-20 vol% SiC Composites Synthesized by Mechanical Alloying and Spark Plasma Sintering. Transactions of the Indian Ceramic Society. 2023;82(2):122-8. 10.1016/j.mtcomm.2022.103921
  61. Wu J, Kai X, Guan C, Xu Z, Miao C, Cao R, et al. Microstructure evolution and mechanical properties of in-situ ZrB2/Al7085 nanocomposites during hot rolling deformation. Materials Today Communications. 2022;32:103921. 10.1016/j.mtcomm.2022.103921
  62. Csanádi T, Vojtko M, Sedlák R, Naughton-Duszová A, Pędzich Z, Dusza J. Anisotropic dislocation nucleation in ZrB2 grains and deformation behaviour of constituents of ZrB2-SiC and ZrB2-B4C composites during nanoindentation. Journal of the European Ceramic Society. 2020;40(7):2674-82. 10.1016/j.jeurceramsoc.2019.12.024
  63. Nayebi B, Parvin N, Asl MS, Motallebzadeh A, Shokouhimehr M. Nanostructural and nanoindentation characterization of ZrB2 ceramics toughened with in-situ synthesized ZrC. International Journal of Refractory Metals and Hard Materials. 2021;94:105391. 10.1016/j.ijrmhm.2020.105391
  64. Asl MS, Nayebi B, Motallebzadeh A, Shokouhimehr M. Nanoindentation and nanostructural characterization of ZrB2–SiC composite doped with graphite nano-flakes. Composites Part B: Engineering. 2019;175:107153. 10.1016/j.compositesb.2019.107153
Volume 39, Issue 2
TRANSACTIONS B: Applications
February 2026
Pages 281-291