Thermodynamic Simulation of an Efficient Flash Ironmaking Technology for Chadormalu Mining and Industrial Company

Document Type : Original Article

Authors

Department of Materials Science and Engineering, Sharif University of Technology, Tehran, Iran

Abstract

The Flash Ironmaking Technology (FIT) utilizing methane (CH4) and air blast (containing 21% oxygen) has been exclusively simulated and calculated for the Chadormalu Mining and Industrial Company (CMIC). The obtained results based on thermodynamic simulation and heat and material balance calculations of the FIT have revealed that a total rate of 70.405 tons/h preheated CH4 is required for the annual production of one million tons of hot metal with 95% metallization. 47% of the methane acts as a reducing agent, and the rest burns with 764.489 tons/h preheated air blast (including 20% excess) to provide 1078 GJ/h energy for running the process at 1600 ˚C (1873 K). Accordingly, 193.134 tons/h carbon dioxide (CO2) is emitted through the process, equivalent to 1.550 tons for every ton of produced hot metal. It indicates that the simulated FIT is eco-friendlier than the blast furnace and coal-based direct reduction ironmaking processes while eliminating coke-making, pelletization or gas-reforming units.

Graphical Abstract

Thermodynamic Simulation of an Efficient Flash Ironmaking Technology for Chadormalu Mining and Industrial Company

Keywords

Main Subjects


  1. Yearbook SS. World Steel Association: Brussels. Belgium; 2014.
  2. Association WS. Fact sheet: energy use in the steel industry. Worldsteel Committee on Economic Studies Brussels, Brussels. 2016. https://worldsteel.org/wp-content/uploads/Fact-sheet-Energy-use-in-the-steel-industry.pdf
  3. Anameric B, Kawatra SK. Properties and features of direct reduced iron. Mineral processing and extractive metallurgy review. 2007;28(1):59-116. https://doi.org/10.1080/08827500600835576
  4. World direct reduction statistics. 2023, Midrex Technologies Incorporation: New Jersey, USA. https://www.midrex.com/wp-content/uploads/MidrexSTATSBook2022.pdf
  5. Chen Y, Zuo H. Review of hydrogen-rich ironmaking technology in blast furnace. Ironmaking & Steelmaking. 2021;48(6):749-68. https://doi.org/10.1080/03019233.2021.1909992
  6. Wu X, Wang S, Fang H, Xu Z, Che P, Acquah AK. Study on semi-coke as an alternative fuel for blast furnace injection coal. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. 2022;44(2):5562-73. https://doi.org/10.1080/15567036.2022.2027577
  7. Xing X. Effects of coal interactions during cokemaking on coke properties under simulated blast furnace conditions. Fuel Processing Technology. 2020;199:106274. https://doi.org/10.1016/j.fuproc.2019.106274
  8. Helle H, Helle M, Saxen H. Nonlinear optimization of steel production using traditional and novel blast furnace operation strategies. Chemical Engineering Science. 2011;66(24):6470-81. https://doi.org/10.1016/j.ces.2011.09.006
  9. Sadrnezhaad S. Direct Reduced Iron an Advantageous Charge Material for Induction Furnaces. International Journal of Engineering. 1990;3(1):37-48. https://www.ije.ir/article_71018.html
  10. Zare Ghadi A, Valipour M, Biglari M. Transient entropy generation analysis during wustite pellet reduction to sponge iron. International Journal of Engineering, Transactions B: Applications, . 2018;31(8):1274-82. https://doi.org/10.5829/ije.2018.31.08b.16
  11. Paswan MK, Mukherjee C. Economic analysis of transportation directly reduced iron (dri) through ship. International Journal of Services Technology and Management. 2012;17(2-4):251-66. https://doi.org/10.1504/IJSTM.2012.048540
  12. Towhidi N. Reoxidation rate of sponge iron pellets, briquettes and iron powder compressed to various compressions in air. International Journal of Engineering. 1988;1(2):111-6. https://www.ije.ir/article_70983.html
  13. Komatina M, GUDENAU HW. The sticking problem during direct reduction of fine iron ore in the fluidized bed. Metallurgical and Materials Engineering. 2018. https://doi.org/10.30544/378
  14. Yi L, Huang Z, Jiang T. Sticking of iron ore pellets during reduction with hydrogen and carbon monoxide mixtures: behavior and mechanism. Powder Technology. 2013;235:1001-7. https://doi.org/10.1016/j.powtec.2012.11.043
  15. Chakraborty I, Sinha S. Refractories for Direct Iron Reduction Processes. https://www.researchgate.net/profile/Indra-Chakraborty-3/publication/344770108_OPTIMISATION_OF_BLAST_FURNACE_TROUGH_LINING_REFRACTORY_PERFORMANCE/links/614c1ee0519a1a381f796959/OPTIMISATION-OF-BLAST-FURNACE-TROUGH-LINING-REFRACTORY-PERFORMANCE.pdf
  16. Gielen D, Moriguchi Y. CO2 in the iron and steel industry: an analysis of Japanese emission reduction potentials. Energy policy. 2002;30(10):849-63. https://doi.org/10.1016/S0301-4215(01)00143-4
  17. Li X, Sun W, Zhao L, Cai J. Material metabolism and environmental emissions of BF-BOF and EAF steel production routes. Mineral Processing and Extractive Metallurgy Review. 2018;39(1):50-8. https://doi.org/10.1080/08827508.2017.1324440
  18. Dahui XX, Wang. Reducing greenhouse gas emissions from energy consumption activities by the iron and steel industry in East China. Energy sources. 1999;21(6):541-6. https://doi.org/10.1080/00908319950014669
  19. Zhang X, Jiao K, Zhang J, Guo Z. A review on low carbon emissions projects of steel industry in the World. Journal of cleaner production. 2021;306:127259. https://doi.org/10.1016/j.jclepro.2021.127259
  20. Kemori N, Denholm W, Kurokawa H. Reaction mechanism in a copper flash smelting furnace. Metallurgical and Materials Transactions B. 1989;20:327-36. https://doi.org/10.1007/BF02696985
  21. Sohn HY, Mohassab Y. Development of a novel flash ironmaking technology with greatly reduced energy consumption and CO 2 emissions. Journal of Sustainable Metallurgy. 2016;2:216-27. https://doi.org/10.1007/s40831-016-0054-8
  22. Sohn HY, Fan D-Q, Abdelghany A. Design of novel flash ironmaking reactors for greatly reduced energy consumption and CO2 emissions. Metals. 2021;11(2):332. https://doi.org/10.3390/met11020332
  23. Abdelghany A, Fan D-Q, Sohn H. Novel flash ironmaking technology based on iron ore concentrate and partial combustion of natural gas: a CFD study. Metallurgical and Materials Transactions B. 2020;51:2046-56. https://doi.org/10.1007/s11663-020-01909-6
  24. Pinegar H, Moats MS, Sohn H. Flowsheet development, process simulation and economic feasibility analysis for novel suspension ironmaking technology based on natural gas: Part 1–Flowsheet and simulation for ironmaking with reformerless natural gas. Ironmaking & Steelmaking. 2012;39(6):398-408. https://doi.org/10.1179/1743281211Y.0000000053
  25. Wang R-r, Zhang J-l, Liu Y-r, Zheng A-y, Liu Z-j, Liu X-l, et al. Thermal performance and reduction kinetic analysis of cold-bonded pellets with CO and H 2 mixtures. International Journal of Minerals, Metallurgy, and Materials. 2018;25:752-61. https://doi.org/10.1007/s12613-018-1623-6
  26. Yang Y, Bao Q, Guo L, Wang Z, Guo Z. Numerical simulation of flash reduction in a drop tube reactor with variable temperatures. International Journal of Minerals, Metallurgy and Materials. 2022;29(2):228-38. https://doi.org/10.1007/s12613-020-2210-1
  27. Chen F, Mohassab Y, Jiang T, Sohn HY. Hydrogen reduction kinetics of hematite concentrate particles relevant to a novel flash ironmaking process. Metallurgical and Materials Transactions B. 2015;46:1133-45. https://doi.org/10.1007/s11663-015-0332-z
  28. Elzohiery M, Fan D, Mohassab Y, Sohn H. Kinetics of hydrogen reduction of magnetite concentrate particles at 1623–1873 K relevant to flash ironmaking. Ironmaking & Steelmaking. 2021;48(5):485-92. https://doi.org/10.1080/03019233.2020.1819942
  29. Wang H, Sohn H. Hydrogen reduction kinetics of magnetite concentrate particles relevant to a novel flash ironmaking process. Metallurgical and Materials Transactions B. 2013;44:133-45. https://doi.org/10.1007/s11663-012-9754-z
  30. Qu Y, Xing L, Wang C, Shao L, Zou Z. Kinetic characterization of flash reduction process of hematite ore fines under hydrogen atmosphere. International Journal of Hydrogen Energy. 2020;45(56):31481-93. https://doi.org/10.1016/j.ijhydene.2020.08.196
  31. Fan D-Q, Elzohiery M, Mohassab Y, Sohn H. The kinetics of carbon monoxide reduction of magnetite concentrate particles through CFD modelling. Ironmaking & Steelmaking. 2021;48(7):769-78. https://doi.org/10.1080/03019233.2020.1861857
  32. Fan D, Elzohiery M, Mohassab Y, Sohn H. Rate-enhancement effect of CO in magnetite concentrate particle reduction by H2+ CO mixtures. Ironmaking & Steelmaking. 2021;48(9):1064-75. https://doi.org/10.1080/03019233.2021.1915645
  33. Chen F, Mohassab Y, Zhang S, Sohn HY. Kinetics of the reduction of hematite concentrate particles by carbon monoxide relevant to a novel flash ironmaking process. Metallurgical and Materials Transactions B. 2015;46:1716-28. https://doi.org/10.1007/s11663-015-0345-7
  34. Elzohiery M, Fan D, Mohassab Y, Sohn H. Experimental investigation and computational fluid dynamics simulation of the magnetite concentrate reduction using methane-oxygen flame in a laboratory flash reactor. Metallurgical and Materials Transactions B. 2020;51(3):1003-15. https://doi.org/10.1007/s11663-020-01809-9
  35. (CMIC), C.M.a.I.C. Products of chadormalu mining and industrial co. 2020 http://chadormalu.com/en-us/Products
  36. Tahari MNA, Salleh F, Saharuddin TST, Samsuri A, Samidin S, Yarmo MA. Influence of hydrogen and carbon monoxide on reduction behavior of iron oxide at high temperature: Effect on reduction gas concentrations. International Journal of Hydrogen Energy. 2021;46(48):24791-805. https://doi.org/10.1016/j.ijhydene.2020.06.250
  37. Heidari A, Niknahad N, Iljana M, Fabritius T. A review on the kinetics of iron ore reduction by hydrogen. Materials. 2021;14(24):7540. https://doi.org/10.3390/ma14247540
  38. Changqing H, Xiaowei H, Zhihong L, Zhang C. Comparison of CO2 emission between COREX and blast furnace iron-making system. Journal of environmental sciences. 2009;21:S116-S20. https://doi.org/10.1016/S1001-0742(09)60052-8
  39. Nduagu EI, Yadav D, Bhardwaj N, Elango S, Biswas T, Banerjee R, et al. Comparative life cycle assessment of natural gas and coal-based directly reduced iron (DRI) production: A case study for India. Journal of Cleaner Production. 2022;347:131196. https://doi.org/10.1016/j.jclepro.2022.131196