A Numerical Simulation of Vanadium Redox Flow Batteries

Authors

Mechanical Engineering Department, Babol Noshirvani University of Technology, Babol, Iran

Abstract

The recent penetration of renewable sources in the energy system caused a transformation of the needs of the distribution system and amplified the need of energy storage systems to properly balance the electricity grid. Among electrochemical energy storage devices, all vanadium flow batteries are those of the most promising technologies due to their high efficiency, long lifetime, reliability and independence between installed power and storage capacity. Oppositely, the low energy density and the high costs are preventing this technology from spreading at commercial level, even if many are the opportunities of improvement. In this article, a serpentine flow fields are tested using a numerical simulation for the all vanadium redox flow battery. The development of a three dimensional model for the cathode of a vanadium redox flow batteries is presented. The results were discussed in terms of the uniformity of the reactant distribution, overpotential, velocity and state of the charge through the cell.

Keywords


Divya, K.C., Ostergaard, J., “Battery energy storage technology for power systems—an overview”, Electric Power Systems Research, Vol. 79, (2009), 511–520.
Dhassa, A. D., Natarajana, E., Lakshmi, P., “an investigation of temperature wffects on solar photovoltaic cells and modules”, International Journal of Engineering, Transaction C: Aspects Vol. 27, (2014), 1713-1722.
Alotto, P., Guarnieri, M., Moro, F., “Redox flow batteries for the storage of renewable energy: A review”, Renewable & Sustainable Energy Reviews, Vol. 29, (2014), 325–335.
Ponce de Leon, C., Frıas-Ferrer, A., Gonzalez-Garcıa, J., Szanto, D.A., Walsh, F.C., “Redox flow cells for energy conversion”, Journal of Power Sources, Vol. 160, (2006), 716–732.
Kear, G., Shah, A.A., Walsh, F.C., “Development of the all vanadium redox flow battery for energy storage: a review of technological, financial and policy aspects”, International Journal of Energy Research, Vol. 36, (2011), 1105-1120.
Skyllas-Kazacos, M., Chakrabarti, M.H., Hajimolana, S. A., Mjalli, F.S., Saleem, M., “Progress in Flow Battery Research and Development”, Journal of The Electrochemical Society, Vol. 158, (2011), 55-79.
Weber, A.Z., Mench, M.M., Meyers, J.P., Ross, P.N., Gostick, J.T., Liu, Q., “Redox flow batteries: A review”, Journal of Applied Electrochemistry, Vol. 41, (2011), 1137–1164.
Xu, Q., Zhao, T.S., Leung, P.K., “Numerical investigations of flow field designs for vanadium redox flow batteries”, Applied Energy, Vol. 105, (2013), 47–56.
Kim, D. K., Yoon, S. J., Lee, J., Kim, S., “Parametric study and flow rate optimization of all-vanadium redox flow batteries”, Applied Energy, Vol. 228, (2018), 891-901.
Yin, C., Gao, Y., Guo, S., Tang, H., “A coupled three dimensional model of vanadium redox flow battery for flow field designs”, Energy, Vol. 74, (2014), 886–895.
Xu, Q., Zhao, T.S., “Fundamental models for flow batteries”, Progress in Energy and Combustion Science, Vol. 49, (2015), 40–58.
Shah, A.A., Watt-Smith, M.J., Walsh, F.C., “A dynamic performance model for redox-flow batteries involving soluble species”, Electrochimica Acta, Vol. 53, (2008), 8087–8100.
You, D., Zhang, H., Chen, J., “A simple model for the vanadium redox battery”, Electrochimica Acta, Vol. 54, (2009), 6827–6836.
Pugach, M., Kondratenko, M., Briola, S., Bischi, A., “Zero dimensional dynamic model of vanadium redox flow battery cell incorporating all modes of vanadium ions crossover”, Applied Energy, Vol. 226, (2018), 560-569.
López-Vizcaíno, R, Mena, E, Millán, M, Rodrigo, M, Lobato, J, “Performance of a vanadium redox flow battery for the storage of electricity produced in photovoltaic solar panels”, Renewable Energy, Vol. 114, (2017), 1123-1133.
Suresh, S., Ulaganathan, M., Venkatesan, N., Periasamy, P., Ragupathy, P., “High performance zinc-bromine redox flow batteries: Role of various carbon felts and cell configurations”, Journal of Energy Storage, Vol. 20, (2018), 134-139
Yan, Y., Skyllas-Kazacos, M., Bao, J, “Effects of battery design, environmental temperature and electrolyte flowrate on thermal behaviour of a vanadium redox flow battery in different applications”, Journal of Energy Storage, Vol. 11, (2017), 104-118.
Li, Y., Zhang, X., Bao, J., Skyllas-Kazacos, M., “Studies on optimal charging conditions for vanadium redox flow batteries”, Journal of Energy Storage, Vol. 11, (2017), 191-199.
Bhattacharjee, A, Saha, H, “Development of an efficient thermal management system for Vanadium Redox Flow Battery under different charge-discharge conditions”, Applied Energy, Vol. 230, (2018), 1182-1192
Nield, Donald A., and Adrian Bejan. Convection in porous media. Vol. 3. New York: springer, 2006.