IJE TRANSACTIONS C: Aspects Vol. 31, No. 3 (March 2018) 504-510    Article in Press

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T. Azdast and R. Hasanzadeh
( Received: December 27, 2016 – Accepted in Revised Form: October 12, 2017 )

Abstract    Polyamide 6 (PA6) is used in many applications due to its advantages and improving its properties seems essential. For this purpose in the present study, PA6 was melt compounded with various multi-walled carbon nanotubes (MWCNTs) contents and then was foamed using Azodi carbon amide (ACA) as blowing agent under different injection molding conditions. Morphological properties were investigated using X-ray diffraction (XRD) and scanning electron microscopy (SEM) tests. The results demonstrated that an appropriate distribution of MWCNTs was observed in polymeric matrix and 0.85, 0.94 and 1 Å increase in distance between walls of CNTs was observed. Also, the SEM results illustrated that microcellular structure was achieved in all samples. The results illuminated that mean cell size was improved about 34% in samples containing 1 wt% MWCNT. The tensile properties of samples were investigated and the effect of MWCNTs content was studied on specific tensile and yield strengths. The results indicated that specific tensile strength and yield strength were significantly increased almost 164% and 147% by addition of 1 wt% of MWCNTs, respectively.


Keywords    Foam, Mechanical properties, Nanocomposite, Polymer, XRD


چکیده    پلی آمید6 به دلیل مزایایی که دارد در کاربردهای مختلفی مورد استفاده قرار می­گیرد و بنابراین بهبود خواص آن ضروری به نظر می­رسد. بدین منظور در تحقیق حاضر پلی آمید6 با درصدهای وزنی مختلف نانولوله کربنی چند دیواره اختلاط ذوبی شد و سپس با استفاده از عامل فوم­زای آزودی کربن آمید تحت شرایط فرآیندی مختلف تزریق، فوم شد. خواص ساختاری با استفاده از تست­های پراش اشعه ایکس (XRD) و میکروسکوپ الکترونی روبشی (SEM) بررسی شد. نتایج نشان داد که توزیع مناسبی از نانولوله­های کربنی چند دیواره داخل ماتریس پلیمری حاصل شد به گونه­ای که 85/0، 94/0 و 1 آنگستروم افزایش فاصله در دیواره­های نانولوله­های کربنی مشاهده شد. همچنین نتایج مربوط به تست SEM نشان داد که ساختار میکروسلولی مناسبی حاصل شد و متوسط اندازه سلولی در نمونه­های فوم نانوکامپوزیتی حاوی 1% نانولوله کربنی به میزان 34% بهبود یافت. خواص کششی نمونه­های فوم نانوکامپوزیتی بررسی شد و تاثیر نانولوله­های کربنی بر روی استحکام کششی و استحکام تسلیم ویژه مورد مطالعه قرار گرفت. نتایج حکایت از افزایش 164% و 147% در استحکام کششی ویژه و استحکام تسلیم ویژه در نمونه­های حاوی 1% وزنی نانولوله کربنی داشت.

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